Download Growth and Characterization of Bulk Superconductor Material by Dapeng Chen, Chengtian Lin, Andrey Maljuk, Fang Zhou PDF

By Dapeng Chen, Chengtian Lin, Andrey Maljuk, Fang Zhou

This publication specializes in lately constructed crystal progress concepts to develop huge and top of the range superconducting unmarried crystals. The options utilized are touring solvent floating region (TSFZ) with infrared snapshot furnace, Bridgeman, solution/flux and most sensible seeded resolution progress (TSSG) equipment. The fabrics variety from cuprates, cobaltates to pnictides together with La2CuO4-based (LCO), YBa2Cu3O7-d (YBCO), Bi2Sr2Can−1CunO2n+4+δ (n=1,2,3) (BSCCO) to NaxCoO2. The changed Bridgman “cold finger” process is dedicated to the pnictide process with the highest quality (transition width DTc~0.5 ok) with maximum Tc~38.5 ok of Ba0.68K0.32Fe2A2. The booklet provides a variety of iron-based superconductors with diverse constructions, similar to 1111, 122, 111, eleven and 42622,10-3-8. precise unmarried crystal progress equipment (fluxes, Bridgman, floating zone), the linked tactics and their influence to crystal measurement and caliber are provided. The booklet additionally describes the impression of doping at the constitution and the electrical, magnetic, and superconducting homes of those compounds in a comparative learn of other progress equipment. It describes quite under-, optimum and over-doped with oxygen cuprates (LCO, YBCO and BSCCO) and hole/electron/isovalently doped guardian compounds AFe2As2 (A = Ba, Sr, Ca) (122), chalcogenides AxFe2-ySe2(A = okay, Rb, Cs) (122), and Fe1-dTe1-xSex (11). A evaluation of the present progress applied sciences and destiny development efforts dealing with risky and toxic parts also are presented.

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Müller in 1986 a tremendous work has been done in synthesis of these materials. Here a crystal growth of high-Tc superconductors plays an extremely important role for the fundamental research because physicists strongly need large size and high quality single crystals to study anisotropic physical properties of these materials. For the Bi-based superconductors, a homologous family with a general formula Bi2Sr2Can–1CunOy where n = 1, A. de C. Lin Max Planck Institute for Solid State Research, Stuttgart, Germany © Springer International Publishing Switzerland 2016 D.

Hidaka, Y. Enomoto, M. Suzuki, M. Oda, T. Murakami, J. Cryst. Growth 85, 581 (1987) I. Tanaka, H. Kojima, Nature 337, 21 (1989) I. Tanaka, K. Yamane, H. Kojima, J. Cryst. S. Hosoya, T. Kajitani, K. Hiraga, K. Oh-Ishi, Y. Syono, K. Yamada, Y. Endoh, T. Takahashi, H. Katayama-Yoshida, Jpn. J. Appl. Phys. Ser. 7, 81 (1992) K. V. Menken, Z. A. M. S. Han, H. Unoki, T. Ito, Y. Ohashi, J. Cryst. Growth 137, 479 (1994) T. Ito, K. Oka, Phys. M. A. K. N. A. A. V. Suetin, Phys. A. ), in High-Tc Superconductors: Proceedings of the 12th Anniversary HTS Workshop.

12]; it shows that the liquidus line required for the growth of Y-123 single crystal form solution was extremely narrow in concentration range. Though the attempts to grow Y-123 crystals based on this phase diagram did not quickly yield large single crystals, but the phase diagram researches have put a solid foundation for the understanding of the chemical circumstances around the YBCO, and finally resulted in large and high quality Y-123 crystals owing to the dedications of crystal growth scientists [4, 5, 15].

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